| Head Office: | 9347 - 193 Street, Surrey, B.C., V4N 4E7 | Technical Information: | 1-800-201-8822 or info@mgchemicals.com | ||
| Revision Date: | 08-Aug-97 | Prepared by: | Howard Clark | Emergency: | Phone Canutech (613) 996-6666 Collect 24 hrs |
| Product Code: 421 | Name: Liquid Tin |
| Use: Tin plates copper circuits. | |
| CAS# | Chemical Name | Percentage by weight | ACGIH TWA | Osha Pel | Osha Stel |
| 15872-11-0 | Fluorboric Acid | 10 | 2.5mg/m3 | n/e | n/e |
| 13814-97-6 | Stannous Fluoroborate | 10 | 2mg/m3 | 2mg/m3 | n/e |
| 62-56-6 | Thiourea | 5 | 2.5mg/m3 | n/e | n/e |
| Eyes: | May cause severe eye burns. | ||
| Skin: | May cause severe burns, dermatitis (red, cracked, irritated skin), and ulceration. May cause allergic skin reactions. | ||
| Inhalation: | May cause pulmonary irritation, irritation of the mucus membranes, coughing, and a sore throat. Nausea, headaches, and vomiting may also occur. Inhilation of large doses may damage the tissues of the respiratory system resulting in chemical pneumontis and pulmonary edema. | ||
| Ingestion: | May cause severe burns to the mouth, throat, and esophagus. Thiourea is shown to be toxic via ingestion and shows the following systemic effects: hemorage and other adverse effects on the blood system (i.e. Anemia, bone marrow depression) | ||
| Chronic: | Chronic exposure to thiourea may cause tumors of the liver. |
| Eyes: | Remove contact lenses. Flush with water or saline for 15 minutes. Get medical aid.. | ||
| Skin: | Wash skin with soap and water for 15 minutes. Get medical aid. | ||
| Inhalation: | Immediately remove from exposure to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | ||
| Ingestion: | Do not induce vomiting. If conscious, give 1-2 glasses of water. Get medical aid immediately. |
| Autoignition Temperature | n/a | Flash Point | n/a | LEL / UEL | n/a |
| Extinguishing Media: | n/a | ||||
| General Information: | Will not burn. | ||||
| NFPA Ratings: | Health | 3 | Flammability | 0 | Reactivity | 1 | ||||
| HMIS Ratings: | Health | 3 | Flammability | 0 | Reactivity | 1 | WHMIS Codes | E,D2B | ||
| Spill Procedure: | Provide adequate ventilation. Wear appropriate personal protection. Sprinkle absorbent compound onto spill, then sweep into a plastic container. Wipe up further residue with paper towel and place into container. Wash spill area with soap and water. |
| Handling: | Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Do not ingest or inhale. Do not expose container to heat or flame. |
| Storage: | Keep away from sources of ignition. Store in a cool, dry, well ventilated area, away from incompatible substances. |
| Routes of entry: | Eyes, ingestion, inhalation, and skin. |
| Ventilation: | Use adequate general or local exhaust ventilation to keep airborne concentrations below exposure limits. |
| Personal Protection: | Wear appropriate protective eyeglasses or chemical safety goggles. Wear appropriate protective clothing to prevent skin contact. Use a NIOSH approved respirator when necessary. |
| Physical State: | Liquid | Odor: | pungent | Solubility: | 100% | Evaporation Rate: | similar to water | ||||||||||||
| Boiling Point: | 100C | Specific Gravity: | 1.2 | Vapor Pressure: | 18 | Vapor Density: | n/e | Ph: | 1 |
| Stability: | Stable at normal temperatures and pressures. | ||
| Conditions to avoid: | Extreme heat may cause product to decompose, producing toxic fumes. | ||
| Incompatibilities: | Alkali, alkaline earth metals and other water incompatible substances, strong bases, strong metals, and strong oxidizers. | ||
| Polymerization: | Will not occur. | ||
| Decomposition: | Halogens, halogen acids, possibly carbonyl halides. |
| Sensitization: (effects of repeated exposure) | Exposure to thiourea may cause allergic skin reactions. | ||
| Carcinogenicity: (risk of cancer) | Thiourea is a suspected cancer causing agent; IARC group 2B (animal sufficient evidence); TDLo 151000g/kg/52 weeks (rat) | ||
| Teratogenicity: (risk of malformation in an unborn fetus) | Thiourea has been reported to cause teratogenic effects in humans or during experimental studies on animals at relatively high doses; TDLo 4800 mg/kg | ||
| Reproductive Toxicity (risk of sterility): | Thiourea has been reported to cause reproductive effects in humans or during experimental studies on animals | ||
| Mutangenicity: (risk of heritable genetic effects): | No |
| Lethal Exposure Concentrations: | Ingestion(LD50): | 125 mg/kg (rat) | Inhalation (LC50): | n/e | Skin (LD50): | n/e |
| General Information: | Avoid runoff into storms and sewers which lead into waterways. Water runoff can cause environmental damage. |
| Environmental Impact Data: (percentage by weight) | |||||||||||
| CFC: | 0 | HFC: | 0 | Cl.Solv. | 0 | VOC: | 0 | HCFC: | 0 | ODP: | 0 |
| General Information: | Dispose of in accordance with all local, provincial, state, and federal regulations. Water runoff can cause environmental damage. |
| Consumer Commodity, ORM-D |
| Shipping Name - Fluoroboric Acid Solution, Class 8, UN# 1775, Packing Group - II, Subsidiary Risk - nil, Tape all seems on the carton. Hazard Label required - Corrosive. A double arrow orientation label is required. The shipper must be trained and certified to handle documented dangerous goods. Emergency - phone (613) 996-6666 collect. References - CFR 49, Transport Canada TDG. |
| Federal Express: |
| Complete Fed Ex dangerous goods declaration, Shipping name - Consumer Commodity, Class - ORM-D, UN # - n/a (leave blank), Packing Group - n/a (leave blank), Sub Risk - n/a (leave blank), Packing Instructions - n/a (leave blank), Authorization - n/a (leave blank). Use M.G. Chemicals UN certified outer carton. A double arrow orientation label is required and is already printed on the original outer carton. Change the ORM-D marking on the outer carton to ORM-D-AIR, Tape all seems on the carton. |
| UPS: |
| Complete UPS forms marked "Hazardous Materials Shipping Paper" and "Shipper's Certification for Hazardous Materials" with the following information: Shipping Name - Consumer Commodity, Hazard Class - ORM-D, Label Type - ORM-D-AIR. Use M.G. Chemicals UN certified outer carton. A double arrow orientation label is required and is already printed on the original outer carton. Change the ORM-D marking on the outer carton to ORM-D-AIR, Tape all seems on the carton. Refer to UPS guide for shipping hazardous materials. |
| Shipping Name - Consumer Commodity, Class 8, ID# 8000, Packing Group - n/a (leave blank), Sub risk - n/a (leave blank), Packing instruction - 910, Authorization - n/a (leave blank), Emergency - phone (613) 996-6666 collect. Use M.G. Chemicals UN certified outer carton. A double arrow orientation label is required and is already printed on the original outer carton. Add a class 9 diamond label to outer carton, and mark ID# 8000 below consumer commodity. Tape all seems. For further information refer to IATA regulations, or phone M.G. Chemicals technical service at 1-800-201-8822 |
| Shipping Name - Fluoroboric Acid Solution, Class 8, UN# 1775, Packing Group - II, Subsidiary Risk - nil, IATA Packaging Instructions - 809, Passenger aircraft are restricted to 1L bottles or smaller. Tape all seems on the carton. Hazard Label required - Corrosive. A double arrow orientation label is required. The shipper must be trained and certified to handle documented dangerous goods. Emergency - phone (613) 996-6666 collect. References - CFR 49, IATA, Transport Canada TDG. |
| Shipping Name - Fluoroboric Acid Solution, Class 8, UN# 1775, Packing Group - II, Vessel Storage - may be stowed on deck or under deck on a cargo vessel or on a passenger vessel. Hazard Label required - Corrosive. A double arrow orientation label is required. Tape all seems. Emergency - phone (613) 996-6666 collect. For further information refer to IMO regulations or phone M.G. Chemicals technical service at 1-800-201-8822. |
| None of the chemicals in this product have a reportable quantity. |
| This product does not contain any chemicals subject to the reporting requirements of section 313 Title III of the SARA of 1986 and 40 CFR part 372. |
| All substances are TSCA listed. |
| This product does not contain any class 1 ozone depletors. | |
| This product does not contain any class 2 ozone depletors. | |
| This product does not contain any chemicals listed as hazardous air pollutants. |
| This product contains thiourea, listed under chemicals know to the state to cause cancer. |
| Labeling and containers used in this product are listed in compliance with Consumer Chemicals and Container regulations. |
| Chemicals in this product are listed on the Domestic Substances List in the Canadian Environmental Protection Act | |
| This product does not contain any ozone depleting substances. |
| Labeling, product identity, net quantity declaration, minimum printing type size heights, and packaging of this product is in compliance with the Consumer Packaging and Labeling Act and Regulations. This product is not slack filled in accordance to chapter 4 prohibitions. |
| Definitions: | n/a = not applicable, n/e = not established |
| Disclaimer: | This material safety data sheet is provided as an information resource only. M.G. Chemicals believes the information contained herein is accurate and compiled from reliable sources. It is the responsibility of the user to verify its validity. The buyer assumes all responsibility of using and handling the product in accordance with federal, state, and local regulations. |